常用氧化剂性能研究

用四种常用的氧化剂:高锰酸钾、漂白粉、NaClO和H2O2/Fe2+对大港油田港深11井酸化废水进行了处理。考察了氧化剂的投加量、氧化时间和pH值对酸化废水色度和COD去除率的影响。实验结果表明,在最佳条件下,H2O2/Fe2+对酸化废水的色度和COD的去除率最高;用高锰酸钾处理废水,其COD去除率较高,但脱色效果差;而漂白粉和NaClO的脱色率较高,但其氧化能力有限。建议油田用氧化法处理废水时应采用H2O2/Fe2+催化氧化体系。     

化学活化法制取污泥衍生吸附剂的实验研究

用有机污泥按照一定的工艺制作污泥衍生吸附剂。结果表明，氯化锌作为化学活化剂在吸附剂的生成过程中起到了关键作用，热解温度是影响吸附剂性能的最主要因素，750℃是最佳热解温度。     

Chemical Composition and Acidity of Rain at the Gulf of Iskenderun,North-East Mediterranean

The purpose of the present work was to investigate the chemistry of rain in the Gulf of Iskenderun, North East Mediterranean, Turkey. The Gulf region has a large number of industries. Main industries existing in the region are iron and steel works, fertilizer plants, a cement plant, and several medium and mini size steel mills in addition to the international pipe line terminals. This study aims to apportion the local sources contributing to the overall pollution of the region. To this end a precipitation sampling program was started in January 2000, and over 48 precipitation samples were collected from each of 5 stations located at Iskenderun city center, Iskenderun industrial zone, Payas city center, the campus of Iskenderun Technical College and the campus of Mustafa Kemal University. Samples were analysed for pH, NO₃ ⁺, Cl^-. Ca, Al, Ba, Na, Cd, Co, Cr, Cu, Pb, Li, Mg, Mn, Ni, Zn, Fe, K. Concentrations of metal ions were determined by ICP-AES. NO₃ ^- ions and pH were determined by using NO₃ ^- selective electrode and pH meter, respectively.pH values of the collected samples at the industrial zone and at Payas city center, ranged between 5.02 and 7.38, respectively. NO₃ ^- and metal ions concentrations were highly variable. Concentrations of Ca and Fe ions were higher in the industrial zone and Payas city center. In the other three stations, concentrations of metal ions and NO₃ ^- ion were lower than that of industrial zone and the values of pH ranged between 6 and 7.4. The average pH values at Iskenderun Gulf showed that the precipitation was not acidic, because of the high concentration of Ca. The highest concentrations of Na and Cl ions were recorded in the University campus because the campus is located by the Mediterranean Sea.     

提高化学需氧量质控合格率的研究

大庆油田化工总厂废水中化学需氧量（COD）的测定采用库仑法。为了提高质控合格率，从人员素质、仪器设备、电级内液等9个方面分析寻找导致误差的主要影响因素并制定对策。同时对影响电极内液及消解的因素进行正交实验确定最佳条件。结果使库仑法质控合格率由90％提高到95％，测定38次标样全部合格。     

论环保意识与现代化工企业的营销观

回顾了市场营销对企业发展的核心作用；讨论了环保意识的增强对营销活动的影响以及环保法规与经济调控对企业的巨大压力；介绍了适应时代要求的社会环境营销观的内容及对现代化工企业的影响，并对化工企业如何树立新型营销观进行了探讨。     

TOPHAZOP: a knowledge-based software tool for conducting HAZOP in a rapid, efficient yet inexpensive manner

Hazard and operability (HAZOP) studies constitute an essential step in the risk analysis of any chemical process industry and involve systematic identification of every conceivable abnormal process deviation, its causes and abnormal consequences. These authors have recently proposed optHAZOP as an alternative procedure for conducting HAZOP studies in a shorter span of time than taken by conventional HAZOP procedure, with greater accuracy and effectiveness [Khan, F. I. and Abassi, S. A., optHAZOP. An effective and efficient technique for hazard identification and assessment Journal of Loss Prevention in the Process Industries, 1997, 10, 191–204]. optHAZOP consists of several steps, the most crucial one requires use of a knowledge-based software tool which would significantly reduce the requirement of expert man-hours and speed up the work of the study team. TOPHAZOP (Tool for OPTmizing HAZOP) has been developed to fulfil this need.

The TOPHAZOP knowledge-base consists of two main branches: process-specific and general. The TOPHAZOP framework allows these two branches to interact during the analysis to address the process-specific aspects of HAZOP analysis while maintaining the generality of the system. The system is open-ended and modular in structure to make easy implementation and/or expansion of knowledge. The important features of TOPHAZOP and its performance on an industrial case study are described.     

酒精废水消化液预处理试验研究

高浓度酒精糟液经厌氧生物处理后排出的消化液COD浓度为4500—6000mg/L，SS浓度高这1500—2．600mg,／L，且由于微小沼气泡附着在厌氧污泥上，沉降性能很差，难以与消化液相分离，对后续处理十分不剁。本研兜采用预曝气．化学混凝沉淀组合工艺，对该消化液进行去除高浓度SS的顸处理试验，研究探讨了曝气时间、混凝剂种类和投加量对SS和COD去除效果的影响。试验结果表明，预曝气．化学混凝沉淀组合工艺对消化液SS的去除效果十分显著。当预曝气时间为6．0h，FeCl3投加量为100mg/L时，消化液的SS去除率75．4％，COD去除率24．3％，可为后续的好氧生物处理提供较为有利的水质和负荷条件。     

生物还原-化学沉淀法自烟气中的SO2制备ZnS

采用生物还原—化学沉淀法自烟气中的SO2制备ZnS,将含有Zn(OH)2杂质的粗品ZnS通过化学提纯制得高纯度ZnS。实验结果表明,采用NH4C l-NH3.H2O混合液对含有Zn(OH)2杂质的粗品ZnS进行提纯的优化条件为:每500m g粗品ZnS加入NH4C l与NH3.H2O摩尔比为1∶1、两组分浓度均为3.0m o l/L的10mLNH4C l-NH3.H2O混合液。X射线衍射分析表明,提纯后的产物粉末全部为ZnS,其纯度与ZnS标准试样相当。     

CO2资源化利用的现状及前景

介绍了CO2分离捕集最新工艺——电化学法、膜法、化学循环燃烧法的研究进展。评述分析了CO2的各种资源化应用前景：CO2气体用作生物碳源、辅助注射成型剂及有机物（如氨基甲酸酯、表面活性剂）合成原料等；液态CO2用于人造金刚石、热泵干燥、超临界CO2萃取及固体干冰冷喷射清洗等。CO2作为一种潜在的丰富碳源，应不断研发其新的应用领域，加快其工业化应用。     

野生一年蓬的开发利用

阐述了野生植物一年蓬的植物学特性、分布习性、化学成分、开发利用价值等，为其进一步开发利用乃至产业化、现代化生产提供参考。